The fluoride ion displacement of carbohydrate trifluoromethanesulphonates using tris(dimethylamino)sulphonium difluorotrimethylsilicate (TASF) provides a convenient route to deoxyfluoro sugars; the rapidity of the reaction makes it of interest for the potential synthesis of fluorinated-carbohydrate radiopharmaceuticals for use in medical imaging.
W. A. Szarek, G. W. Hay and B. Doboszewski, J. Chem. Soc., Chem. Commun., 1985, 663 DOI: 10.1039/C39850000663
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