Issue 5, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

The origin of the amide formed in the photochemical reactions of aminimides: rearrangement of trimethylammonio-N-diphenylphosphinoylimide to N-(dimethylaminomethyl)diphenylphosphinic amide

Sally Freeman Martin  and  J. P. Harger  

Abstract

The principal photochemical reaction of Ph2P(O)[N with combining macron]–NMe3 in dimethyl sulphoxide or methanol is rearrangement to Ph2P(O)NHCH2NMe2 which subsequently decomposes to give the amide Ph2P(O)NH2; rearrangement also occurs with PhCO[N with combining macron]–NMe3but is apparently not the major reaction pathway

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39850000241
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 241-242

Permissions

Request permissions

The origin of the amide formed in the photochemical reactions of aminimides: rearrangement of trimethylammonio-N-diphenylphosphinoylimide to N-(dimethylaminomethyl)diphenylphosphinic amide

S. F. Martin and J. P. Harger, J. Chem. Soc., Chem. Commun., 1985, 241 DOI: 10.1039/C39850000241

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements