Stabilization of copper(I) in aqueous solutions by ligation with the saturated tetra-aza macrocyclic ligand 1,4,5,7,7,8,11,12,14,14,-decamethyl-1,4,8,11-tetra azacyclotetradecane
Abstract
The title perchlorate complex is stable in air-saturated aqueous solutions and is reversibly oxidized to the divalent complex at +0.47 V vs. Ag/Agcl.