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Deuterium labelling studies show that, contrary to earlier proposals, at a rhodium centre of cis-cyclo-octeme into the allylic alcohol, cyclo-oct-2-en-1-ol (1) involved oxygenative attack at a vinylic centre and double bond migration; a finding considered to have mechanistic implications for related co-oxygenations at group 8 metal centres.
G. Read and J. Shaw, J. Chem. Soc., Chem. Commun., 1984, 1313 DOI: 10.1039/C39840001313
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