Issue 17, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

A triply-bridged binuclear hydrazidomolybdenum(V) complex with terminal, bridging, and ‘dangling’ thiolate ligands. The chemical and structural characterization of [HNEt3]2[Mo2(NNPh)(NNHPh)(SCH2CH2S)3(SCH2CH2SH)]·2/3H2NNHPh

Tze-Chen Hsieh,   Kassu Gebreyes  and  J. Zubieta  

Abstract

The title compound has been obtained by treating [Mo(NNHPh)2(butane-2,3-diolate)2]·H2NNHPh with excess of dimercaptoethane in methanol; X-ray crystallography reveals the first example of a binuclear bis-hydrazido complex and a unique instance of a molybdenum(V) complex exhibiting thiolate co-ordination trans to a strongly π-bonding group.

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Article information

DOI
https://doi.org/10.1039/C39840001172
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 1172-1174

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A triply-bridged binuclear hydrazidomolybdenum(V) complex with terminal, bridging, and ‘dangling’ thiolate ligands. The chemical and structural characterization of [HNEt3]2[Mo2(NNPh)(NNHPh)(SCH2CH2S)3(SCH2CH2SH)]·2/3H2NNHPh

T. Hsieh, K. Gebreyes and J. Zubieta, J. Chem. Soc., Chem. Commun., 1984, 1172 DOI: 10.1039/C39840001172

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