SCHEDULED MAINTENANCE
Preparations of the enzyme isopenicillin N-synthetase from Cephalosporium acremonium CO 728 convert the modified substrates δ-(L-α-aminoadipoyl)-L-cysteinyl-D-(–)-isoleucine and δ-(L-α-aminoadipoyl)-L-cysteinyl-D-norvaline into cepham-type products, which have been isolated and their structures established.
J. E. Baldwin, R. M. Adlington, N. J. Turner, B. P. Domayne-Hayman, H. Ting, A. E. Derome and J. A. Murphy, J. Chem. Soc., Chem. Commun., 1984, 1167 DOI: 10.1039/C39840001167
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