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Issue 17, 1984
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Pathways for reduction of nickelocene under CO

Abstract

Cyclic voltammetry under CO has been used to show that the short-lived nickelocene anion splits into NiCp and Cp(Cp = C5H5) fragments; trapping of the NiCp moiety with CO leads to [Ni(CO)Cp], which under high CO pressure loses a further Cp to give Ni(CO)4.

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Article information


J. Chem. Soc., Chem. Commun., 1984, 1137-1138
Article type
Paper

Pathways for reduction of nickelocene under CO

J. D. Payne and N. E. Murr, J. Chem. Soc., Chem. Commun., 1984, 1137
DOI: 10.1039/C39840001137

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