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Issue 15, 1984
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1,4-Fragmentatioin of γ-tributylstannyl alcohols by a hypervalent organoiodine compound: a new synthesis of unsaturated carbonyl compounds

Abstract

1,4-Fragmentation of γ-tributylstannyl alcohols using iodosylbenzene, boron trifiluoride–diethyl ether, and dicyclohexycarbodiimide produces unsaturatd carbonyl compounds; the fragmentation, combined with conjugate addition of tributylstannyl-lithium and reduction or alkylation, offers an efficient procedure for the reductive and alkylative ring opening of cyclic vinyl ketones.

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Article type: Paper
DOI: 10.1039/C39840001007
J. Chem. Soc., Chem. Commun., 1984, 1007-1008

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    1,4-Fragmentatioin of γ-tributylstannyl alcohols by a hypervalent organoiodine compound: a new synthesis of unsaturated carbonyl compounds

    M. Ochiai, T. Ukita, Y. Nagao and E. Fujita, J. Chem. Soc., Chem. Commun., 1984, 1007
    DOI: 10.1039/C39840001007

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