Although the scalar relaxation between the quadrupolar nucleus 17O and a phosphorus atom to which it is bonded can cause extreme broadening of the 31P resonance, it does not decouple the 31P nucleus even in a tightly coupled system; consequently the 31P–31P geminal coupling constant in pyrophosphate can easily be measured at low magnetic field.
G. Lowe and B. V. L. Potter, J. Chem. Soc., Chem. Commun., 1984, 877 DOI: 10.1039/C39840000877
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