Issue 13, 1984

An improved synthesis of triquinacene derivatives. Two-step regioselective oxidation of endo-dicyclopentadiene to Deslongchamps's diketone

Abstract

endo-Dicyclopentadiene can be regioselectively oxidised, in two steps, to Deslongchamps's diketone (3), from which either 2,3-dihydrotriquinacene-2-one (13) or the corresponding conjugated ketone (14) can be selectively prepared in excellent overall yields.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 825-826

An improved synthesis of triquinacene derivatives. Two-step regioselective oxidation of endo-dicyclopentadiene to Deslongchamps's diketone

E. Carceller, M. L. Garcia, A. Moyano and F. Serratosa, J. Chem. Soc., Chem. Commun., 1984, 825 DOI: 10.1039/C39840000825

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