Issue 8, 1984

Generation and trapping of a phosphinine sulphide

Abstract

With sulphur at ca. 140 °C in xylene, 4,5-dimethyl-2-phenylphosphinine gives a transient P-sulphide which reacts with 2,3-dimethylbutadiene as a dienophile through its 1,6 positions and with dimethyl acetylenedicarboxylate as a diene through its 1,4 positions.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 508-509

Generation and trapping of a phosphinine sulphide

J. Alcaraz and F. Mathey, J. Chem. Soc., Chem. Commun., 1984, 508 DOI: 10.1039/C39840000508

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