Issue 6, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

The synthesis and structure of [CO(η-C5Me5)Et{P(p-tolyl)3}] cation: a model for the β-elimination transition state

Robert B. Cracknell,   A. Guy Orpen  and  John L. Spencer  

Abstract

Protonation of [Co(η-C5Me5)(C2H4){P(p-tolyl)3}] affords the ethyl cation [Co(η-C5Me5)Et{P(pp-tolyl)3}]+ in which there is a strong three-centre interaction between the metal and a β-C–H, as indicated by 1H and 13C n.m.r. and by a single crystal X-ray diffraction study of the tetrafluoroborate salt.

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Article information

DOI
https://doi.org/10.1039/C39840000326
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 326-328

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The synthesis and structure of [CO(η-C5Me5)Et{P(p-tolyl)3}] cation: a model for the β-elimination transition state

R. B. Cracknell, A. G. Orpen and J. L. Spencer, J. Chem. Soc., Chem. Commun., 1984, 326 DOI: 10.1039/C39840000326

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