Issue 1, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthetic transformations using iodotrimethylsilane: regiospecific deoxygenation of the dihydroxyacetone moiety at C-17 of corticoid steroids

Mitsuteru Numazawa,   Masao Nagaoka  and  Yurie Kunitama  

Abstract

Corticoids having the dihydroxyacetone group [double bond splayed left]C(17)(OH)–C(20)(O)-C(21)H2OH are regiospecifically converted into 21-hydroxy-20-ketones in high yields by treatment with iodotrimethylsilane.

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Article information

DOI
https://doi.org/10.1039/C39840000031
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 31-32

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Synthetic transformations using iodotrimethylsilane: regiospecific deoxygenation of the dihydroxyacetone moiety at C-17 of corticoid steroids

M. Numazawa, M. Nagaoka and Y. Kunitama, J. Chem. Soc., Chem. Commun., 1984, 31 DOI: 10.1039/C39840000031

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