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Issue 18, 1983
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Spectroscopic evidence for the formation of tri-µ-carbonyl-bis-[(η5-cyclopentadienyl)iron] on photolysis of bis[(dicarbonyl)(η5-cyclopentadienyl)iron] in low temperature matrices

Abstract

Photolysis of [{(η5-C5H5)Fe(CO)2}2] in CH4(12 K) and polyvinyl chloride film (12–77 K) matrices leads to the formation of a novel species proposed, on the basis of i.r. evidence including 13CO enrichment and u.v.– visible spectra, to be the CO-bridged dimer [(µ-CO)3{(η5-C5H5)Fe}2].

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Article type: Paper
DOI: 10.1039/C39830001022
Citation: J. Chem. Soc., Chem. Commun., 1983,0, 1022-1024

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    Spectroscopic evidence for the formation of tri-µ-carbonyl-bis-[(η5-cyclopentadienyl)iron] on photolysis of bis[(dicarbonyl)(η5-cyclopentadienyl)iron] in low temperature matrices

    R. H. Hooker, K. A. Mahmoud and A. J. Rest, J. Chem. Soc., Chem. Commun., 1983, 0, 1022
    DOI: 10.1039/C39830001022

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