An X-ray crystal structure determination shows that in [HBeN(Me)C2H4NMe2]2 the hydrogen atom bound to beryllium occupies a terminal position with amido nitrogen atoms as the bridging atoms in a four-membered Be2N2ring; the metal and nitrogen atoms achieve four-co-ordination via formation of four- and five-membered rings with the diamine.
N. A. Bell, G. E. Coates, M. L. Schneider and H. M. M. Shearer, J. Chem. Soc., Chem. Commun., 1983, 828 DOI: 10.1039/C39830000828
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