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Issue 10, 1983
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Preparation and structural characterisation of [NEt4]2[Mn2(SCH2CH2S)4], a stable manganese(III)–thiolate dimer

Abstract

Controlled air oxidation of [Mn(edt)2]2–(edt = ethane-1,2-dithiolate) in ethanolic solution yield deep green [Mn2(edt)4]2– which has been structurally characterized as its NEt4+ salt; the anion consists of a bis-thiolate-bridged manganese(III) dimer, establishes the existence of a stable manganese(III)–thiolate bond, and supports the possible occurrence of this linkage in manganese(III)-containing biological systems.

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Article type: Paper
DOI: 10.1039/C39830000558
Citation: J. Chem. Soc., Chem. Commun., 1983,0, 558-560

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    Preparation and structural characterisation of [NEt4]2[Mn2(SCH2CH2S)4], a stable manganese(III)–thiolate dimer

    G. Christou and J. C. Huffman, J. Chem. Soc., Chem. Commun., 1983, 0, 558
    DOI: 10.1039/C39830000558

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