Issue 10, 1983

Preparation and structural characterisation of [NEt4]2[Mn2(SCH2CH2S)4], a stable manganese(III)–thiolate dimer

Abstract

Controlled air oxidation of [Mn(edt)2]2–(edt = ethane-1,2-dithiolate) in ethanolic solution yield deep green [Mn2(edt)4]2– which has been structurally characterized as its NEt4+ salt; the anion consists of a bis-thiolate-bridged manganese(III) dimer, establishes the existence of a stable manganese(III)–thiolate bond, and supports the possible occurrence of this linkage in manganese(III)-containing biological systems.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 558-560

Preparation and structural characterisation of [NEt4]2[Mn2(SCH2CH2S)4], a stable manganese(III)–thiolate dimer

G. Christou and J. C. Huffman, J. Chem. Soc., Chem. Commun., 1983, 558 DOI: 10.1039/C39830000558

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements