Issue 8, 1983

A new undecametal rhodium carbonyl cluster consisting of three condensed octahedral units. Synthesis and crystal structure of the [Rh11(CO)23]3– trianion

Abstract

The anion [RH11(CO)23]3–, obtained through oxidation of [RH7(CO)16]3– or various redox considerations, contains a metal polyhedron of ideal D3h symmetry which can be described as being the result of a face-to-face condensation of three octahedral sub-units.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 453-455

A new undecametal rhodium carbonyl cluster consisting of three condensed octahedral units. Synthesis and crystal structure of the [Rh11(CO)23]3– trianion

A. Fumagalli, S. Martinengo, G. Ciani and A. Sironi, J. Chem. Soc., Chem. Commun., 1983, 453 DOI: 10.1039/C39830000453

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