Issue 8, 1983

Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum–thallium complex, [MoTl(SC6F5)4(η-C5H5)]

Abstract

Paramagnetic diene complexes [MoX2(diene)(η-C5H5)](X = Cl, Br, I, SAr) give well resolved e.s.r. spectra in solution; reaction with TISC6F5 produces the unusual fluxional, bimetallic complex [MoTl(SC6F5)4(η-C5H5)].

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 452-453

Paramagnetic diene complexes of molybdenum(III) and a transformation into a diamagnetic, fluxional molybdenum–thallium complex, [MoTl(SC6F5)4(η-C5H5)]

J. L. Davidson, K. Davidson and W. E. Lindsell, J. Chem. Soc., Chem. Commun., 1983, 452 DOI: 10.1039/C39830000452

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