Issue 8, 1983

Chlorination of 1,5-anhydro-4,6,-o-benzylidene-2,3-dideoxy-3-nitro-D-arabino-hex-1-enitol; highly stereoselective preparation of α-D-glucopyranosyl chloride and ω-chloroalkyl β-D-glucopyranosides

Abstract

Chlorination of 1,5-anhydro-4,6-O-benzylidene-2,3-dideoxy-3-nitro-D-arabino-hex-1-enitol in cyclic ethers such as tetrahydrofuran stereoselectively afforded the ω-chloroalkyl β-D-glycopyranoside derivatives, whereas in 1,4-dioxane α-D-glycopyranosyl chloride was obtained in high yield.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 449-450

Chlorination of 1,5-anhydro-4,6,-o-benzylidene-2,3-dideoxy-3-nitro-D-arabino-hex-1-enitol; highly stereoselective preparation of α-D-glucopyranosyl chloride and ω-chloroalkyl β-D-glucopyranosides

T. Sakakibara, Y. Nomura, K. Yoshino and R. Sudoh, J. Chem. Soc., Chem. Commun., 1983, 449 DOI: 10.1039/C39830000449

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements