Issue 6, 1983

Synthesis and molecular structures of nido-[9-(η-C5H5)-7,8,9-C2NiB8H11], nido-[9-(η-C5H5)-µ10,11-(Ph3PAu)-7,8,9-C2NiB8H10], and closo-[1,3-(η-C5H5)2-1,2,3,4-CrCCrCB8H10]; evidence for a multiple metal–metal bond in a dimetallacarbaborane

Abstract

From nido-5,6-C2B8H12, the compounds nido-[9-(η-C5H5)-7,8,9-C2NiB8H11], nido-[9-(η-C5H5)-µ10, 11-(Ph3PAu)-7,8,9-C2NiB8H10], and closo-[1,3-(η-C5H5)2-1,2,3,4-CrCCrCB8H10] have been synthesised, and their structure identities established by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1983, 277-279

Synthesis and molecular structures of nido-[9-(η-C5H5)-7,8,9-C2NiB8H11], nido-[9-(η-C5H5)-µ10,11-(Ph3PAu)-7,8,9-C2NiB8H10], and closo-[1,3-(η-C5H5)2-1,2,3,4-CrCCrCB8H10]; evidence for a multiple metal–metal bond in a dimetallacarbaborane

G. K. Barker, N. R. Godfrey, M. Green, H. E. Parge, F. G. A. Stone and A. J. Welch, J. Chem. Soc., Chem. Commun., 1983, 277 DOI: 10.1039/C39830000277

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