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Issue 5, 1983
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X-Ray crystal and molecular structure of the complex between dibenzo-14-crown-4 and LiSCN

Abstract

The crystal structure of the title compound shows that in the complex the Li+ cation is penta-co-ordinated to the 4 ethereal oxygens and to the N of the SCN anion, in a nearly square pyramidal geometry where Li is 0.79 Å out of the plane of the oxygens; the average Li–O distance is 2.04 Å and Li–N is 1.96 Å.

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Article information


J. Chem. Soc., Chem. Commun., 1983, 208-209
Article type
Paper

X-Ray crystal and molecular structure of the complex between dibenzo-14-crown-4 and LiSCN

G. Shoham, W. N. Lipscomb and U. Olsher, J. Chem. Soc., Chem. Commun., 1983, 208
DOI: 10.1039/C39830000208

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