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Issue 2, 1983

closonido-Cluster isomerism in metallacarbaboranes via a change of metal valency state: molecular structure of µ-1,2-acetato-2-hydrido-2,10-bis(triphenylphosphine)-closo-1,2-carbairidadecaborane

Abstract

The iridium(III)closo-cluster structure of [µ-1,2-(MeCO·O)-2-H-2,10-(PPh3)2-closo-1,2-ClrB8H7], which also contains a novel acetate bridge, contrasts with the otherwise ostensibly isoelectronic iridium (V)iso-nido-cluster structure of [(PPh3)(Ph2P[graphic omitted]H6(OMe)C(OH)}]

Article information


J. Chem. Soc., Chem. Commun., 1983, 83-84
Article type
Paper

closonido-Cluster isomerism in metallacarbaboranes via a change of metal valency state: molecular structure of µ-1,2-acetato-2-hydrido-2,10-bis(triphenylphosphine)-closo-1,2-carbairidadecaborane

J. E. Crook, N. N. Greenwood, J. D. Kennedy and W. S. McDonald, J. Chem. Soc., Chem. Commun., 1983, 83 DOI: 10.1039/C39830000083

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