Issue 20, 1982

Pentafluorophenyl nitrene: a matrix isolated aryl nitrene thet does not undergo ring expansion

Abstract

Photolysis of pentafluorophenyl azide or pentafluorophenyl Isocyanate in low-temperature matrices gives pentafluorophenyl nitrene which, in the presence of CO, may react photochemically but not thermally to give the isocyanate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 1192-1193

Pentafluorophenyl nitrene: a matrix isolated aryl nitrene thet does not undergo ring expansion

I. R. Dunkin and P. C. P. Thomson, J. Chem. Soc., Chem. Commun., 1982, 1192 DOI: 10.1039/C39820001192

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