The newly synthesized iron(II)‘hanging base’ porphyrins (8) and (9) provide evidence that polar groups on the distal side of the heme strongly increase the stability of the oxygenated complexes by reducing the rate constant for dissociation of dioxygen.
M. Momenteau and D. Lavalette, J. Chem. Soc., Chem. Commun., 1982, 341 DOI: 10.1039/C39820000341
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