Issue 4, 1982

The contribution of ring strain to nucleofugality: the first measurement

Abstract

Comparison of eliminative ring fission in a cyclopropane and elimination in an acyclic analogue allows determination of acceleration of elimination by ring strain; a factor of a least 1011.7 has been found, the largest for any heterolytic reaction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 236-237

The contribution of ring strain to nucleofugality: the first measurement

G. Griffiths, S. Hughes and C. J. M. Stirling, J. Chem. Soc., Chem. Commun., 1982, 236 DOI: 10.1039/C39820000236

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