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8,8-Dibromobicyclo[5.1.0]octa-2,4-diene (5) is converted into the cis-bicyclo[3.3.0]octa-2,6-diene(7; X = Ome or OH) by treatment with AgClO4–MeOH or AgClO4–aq. Acetone, respectively; the corresponding exo-monobromide (14;X = H, Y = Br) is similarly converted into (8) by AgClO4–MeOH.
M. S. Baird, W. Nethercott and C. B. Reese, J. Chem. Soc., Chem. Commun., 1982, 224 DOI: 10.1039/C39820000224
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