Issue 4, 1982
From the journal:

Journal of the Chemical Society, Chemical Communications

η3-Allyruthenium(II) complexes as intermediates in substitution and isomerization of diene ligands; the dominant role of steric effects

Terence V. Ashworth,   Anthony A. Chalmers,   Eric Singleton  and  Hester E. Swanepoel  

Abstract

The formation of [Ru(η3-C8H13)L3]PF6 as intermediates in the conversion of [RuH(cod)L3]PF6[cod = cyclo-octa-1,5-diene, L = PMe3, P(OMe)2Ph,PMe2Ph, P(OMe)Ph2, and P(OCH2CMe3)3] into [RuHL4(solvent)]PF6[L = P(OMe)Ph2 and P(OCH2CMe3)3] and [RuHL5]PF6[L = PMe3, P(OMe)2Ph and PMe2Ph] and cyclo-octa-1,3-diene, has been shown be dependent upon the size of L.

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Article information

DOI
https://doi.org/10.1039/C39820000214
Article type
Paper

J. Chem. Soc., Chem. Commun., 1982, 214-215

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η3-Allyruthenium(II) complexes as intermediates in substitution and isomerization of diene ligands; the dominant role of steric effects

T. V. Ashworth, A. A. Chalmers, E. Singleton and H. E. Swanepoel, J. Chem. Soc., Chem. Commun., 1982, 214 DOI: 10.1039/C39820000214

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