Issue 23, 1981
From the journal:

Journal of the Chemical Society, Chemical Communications

Addition of diphenyldiazomethane to hexa-alkoxydimolybdenum(M[triple bond, length as m-dash]M) compounds: characterization of Mo2(OPri)6(N2CPh2)2(pyridine) by X-ray crystallography

Malcolm H. Chisholm,   Kirsten Folting,   John C. Huffman  and  Andrew L. Ratermann  

Abstract

Addition of diphenyldiazomethane (2 equiv.) to hexane solutions of Mo2(OR)6, where R = isopropyl or neopentyl, in the presence of pyridine (py) leads to the formation of the cyrstalline compounds Mo2(OR)6(N2CPh2)2(py), which are shown to contain mixed valence (Mo-Mo)10+ units.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39810001229
Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1229-1231

Permissions

Request permissions

Addition of diphenyldiazomethane to hexa-alkoxydimolybdenum(M[triple bond, length as m-dash]M) compounds: characterization of Mo2(OPri)6(N2CPh2)2(pyridine) by X-ray crystallography

M. H. Chisholm, K. Folting, J. C. Huffman and A. L. Ratermann, J. Chem. Soc., Chem. Commun., 1981, 1229 DOI: 10.1039/C39810001229

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements