SCHEDULED MAINTENANCE
The dimeric d9 PdI dianion [Pd2Cl4(CO)2]2– is shown to have two bridging carbonyl ligands both in the solid state and in solution by X-ray structure analysis and i.r. spectroscopy; this is in contrast with a large number of d8 di- and polymeric metal carbonyl halide complexes where the halide ligands are bridging.
P. L. Goggin, R. J. Goodfellow, I. R. Herbert and A. G. Orpen, J. Chem. Soc., Chem. Commun., 1981, 1077 DOI: 10.1039/C39810001077
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