Issue 20, 1981

Bridging by carbonyl vs. halide ligands: X-ray crystal structure of [NBu4n]2[Pd2Cl4(µ-CO)2]

Abstract

The dimeric d9 PdI dianion [Pd2Cl4(CO)2]2– is shown to have two bridging carbonyl ligands both in the solid state and in solution by X-ray structure analysis and i.r. spectroscopy; this is in contrast with a large number of d8 di- and polymeric metal carbonyl halide complexes where the halide ligands are bridging.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 1077-1079

Bridging by carbonyl vs. halide ligands: X-ray crystal structure of [NBu4n]2[Pd2Cl4(µ-CO)2]

P. L. Goggin, R. J. Goodfellow, I. R. Herbert and A. G. Orpen, J. Chem. Soc., Chem. Commun., 1981, 1077 DOI: 10.1039/C39810001077

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