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Issue 16, 1981
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Isolation and X-ray crystal structure of [Cu(NH3)4H2O.18-crown-6]n2+[PF6]2n a linear face-to-face hydrogen bonded chain copolymer

Abstract

X-Ray crystallography reveals that the [aquo-(tetra-ammine)copper]2+ ion forms a chain copolymer with 18-crown-6 in which each individual crown molecule is involved in no fewer than ten hydrogen bonds with four ammine ligands co-ordinated to the copper(II) centres in adjacent ions.

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Article information


J. Chem. Soc., Chem. Commun., 1981, 849-850
Article type
Paper

Isolation and X-ray crystal structure of [Cu(NH3)4H2O.18-crown-6]n2+[PF6]2n a linear face-to-face hydrogen bonded chain copolymer

H. M. Colquhoun, J. F. Stoddart and D. J. Williams, J. Chem. Soc., Chem. Commun., 1981, 849
DOI: 10.1039/C39810000849

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