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Issue 16, 1981
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The binding of neutral platinum complexes by crown ethers. X-Ray crystal structures of [trans-PtCl2(PMe3)NHdibenzo-18-crown-6] and [{trans-PtCl2(PMe3)NH3}18-crown-6]

Abstract

Complexes of the type trans-PtCl2(L)NH3 where L = PMe3(1), PEt3(2), and NH3(3) co-ordinate to 18-crown-6 (18C6) and dibenzo-18-crown-6 (DBI8C6) by hydrogen bonding of their NH3 ligands, forming the crystalline adducts [(1)–DBI8C6], [(2)–DBI8C6], [(1)2–18C6], [(2)2–18C6], and [(3)–18C6]n which also display considerable stability in solution.

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Article information


J. Chem. Soc., Chem. Commun., 1981, 847-849
Article type
Paper

The binding of neutral platinum complexes by crown ethers. X-Ray crystal structures of [trans-PtCl2(PMe3)NHdibenzo-18-crown-6] and [{trans-PtCl2(PMe3)NH3}18-crown-6]

H. M. Colquhoun, J. F. Stoddart and D. J. Williams, J. Chem. Soc., Chem. Commun., 1981, 847
DOI: 10.1039/C39810000847

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