Issue 12, 1981

Synthesis of a new heteronuclear gold–cobalt cluster. Preparation and X-ray structure determination of tetrakis (triphenylphosphine)-bis(tetracarbonylcobalt)hexagold

Abstract

The reaction of [AU8L7]2+(L = PPh3) with an excess of Li[Co(CO)4] in tetrahydrofuran results in the formation of Au6L4[Co(CO)4]2, the structure of which has been determined by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1981, 583-584

Synthesis of a new heteronuclear gold–cobalt cluster. Preparation and X-ray structure determination of tetrakis (triphenylphosphine)-bis(tetracarbonylcobalt)hexagold

J. W. A. van der Velden, J. J. Bour, B. F. Otterloo, W. P. Bosman and J. H. Noordik, J. Chem. Soc., Chem. Commun., 1981, 583 DOI: 10.1039/C39810000583

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