Methane and a C2–C6 cut containing up to 75% olefins are synthesized from CO and H2 at 199 °C and under atmospheric pressure with a catalyst prepared by the reduction of cobalt(II) acetylacetonate with triethylaluminium with an alkylterphenyl solvent.
M. Blanchard, D. Vanhove, F. Petit and A. Mortreux, J. Chem. Soc., Chem. Commun., 1980, 908 DOI: 10.1039/C39800000908
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