1,3,4-Oxathiazoles, on thermolysis, undergo retro-1,3-dipolar cycloaddition to afford carbonyl compounds and nitrile sulphides, which may be trapped by cycloaddition with alkynes and nitriles.
R. M. Paton, F. M. Robertson, J. F. Ross and J. Crosby, J. Chem. Soc., Chem. Commun., 1980, 714 DOI: 10.1039/C39800000714
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