Issue 3, 1980

Preparation and transmetallation of a neutral magnesium(II) complex of a tetra-aza macrocyclic ligand: X-ray structure of {17,18,19,20-tetrahydrotribenzo[e,i,m][1,4,8,11]tetra-azacyclotetradecinato(2–)}oxovanadium(IV)

Abstract

A neutral magnesium(II) complex has been obtained from reactions of a planar conjugated ‘N4’ macrocyclic ligand (1) with Grignard reagents; it readily undergoes a transmetallation reaction to give a neutral square-pyramidal oxo-vanadium(IV) complex, the structure of which has been determined by X-ray crystallography.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 88-89

Preparation and transmetallation of a neutral magnesium(II) complex of a tetra-aza macrocyclic ligand: X-ray structure of {17,18,19,20-tetrahydrotribenzo[e,i,m][1,4,8,11]tetra-azacyclotetradecinato(2–)}oxovanadium(IV)

A. J. Greenwood, K. Henrick, P. G. Owston and P. A. Tasker, J. Chem. Soc., Chem. Commun., 1980, 88 DOI: 10.1039/C39800000088

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