Issue 3, 1980

The participation effect of halogen atoms in stereospecific Friedel–Crafts alkylations

Abstract

The Friedel–Crafts alkylation of benzene with optically active 1,2-, 1,3-, 1,4-, and 1,5-dihalogenoalkanes gave the corresponding primary phenylalkyl halides with a stereospecificity which depended primarily on the type of terminal halogen or the variation in carbon chain length.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1980, 86-87

The participation effect of halogen atoms in stereospecific Friedel–Crafts alkylations

S. Masuda, M. Segi, T. Nakajima and S. Suga, J. Chem. Soc., Chem. Commun., 1980, 86 DOI: 10.1039/C39800000086

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