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Issue 20, 1979
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Phototranspositions of cyanothiophens: permutation pattern analysis and the chemical trapping of an intermediate 5-thiabicyclo-[2.1.0]pent-2-ene

Abstract

Through their first excited singlet states, cyanothiophens undergo phototranspositions for which permutation pattern analysis and the isolation of furan–thiabicyclopentene adducts from irradiations in furan suggest a mechanism involving 2,5-bonding followed by a ‘walk’ of the sulphur atom.

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Article information


J. Chem. Soc., Chem. Commun., 1979, 881-883
Article type
Paper

Phototranspositions of cyanothiophens: permutation pattern analysis and the chemical trapping of an intermediate 5-thiabicyclo-[2.1.0]pent-2-ene

J. A. Barltrop, A. C. Day and E. Irving, J. Chem. Soc., Chem. Commun., 1979, 881
DOI: 10.1039/C39790000881

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