Issue 17, 1979
From the journal:

Journal of the Chemical Society, Chemical Communications

Pressure dependence of the racemization of tris(pyrrolidyldithiocarbamato)-cobalt(III) in non-aqueous solvents

Geoffrey A. Lawrance,   Surapong Suvachittanont,   Donald R. Stranks,   Peter A. Tregloan,   Lawrence R. Gahan  and  Maxwell J. O'Connor  

Abstract

From activation volume evidence a twist mechanism incorporating a low-spin → high-spin pre-equilibrium in the transition state is indicated for racemization of Co(pyrdtc)3(pyrdtc = pyrrolidyldithio-carbamato) in non-aqueous solvents.

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Article information

DOI
https://doi.org/10.1039/C39790000757
Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 757-758

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Pressure dependence of the racemization of tris(pyrrolidyldithiocarbamato)-cobalt(III) in non-aqueous solvents

G. A. Lawrance, S. Suvachittanont, D. R. Stranks, P. A. Tregloan, L. R. Gahan and M. J. O'Connor, J. Chem. Soc., Chem. Commun., 1979, 757 DOI: 10.1039/C39790000757

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