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Issue 8, 1979
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Synthesis of methyl (R)- and (S)-[18O]phosphorothioates and determination of the absolute configuration at phosphorus of the diastereoisomers of adenosine 5′-(1-thiotriphosphate)

Abstract

A general route for the synthesis of enantiomeric [18O]phosphorothioate esters of known absolute configuration has been developed, and isomer A of adenosine 5′-(1-thiotriphosphate) shown to have the (S)-configuration at Pα.

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Article information


J. Chem. Soc., Chem. Commun., 1979, 364-366
Article type
Paper

Synthesis of methyl (R)- and (S)-[18O]phosphorothioates and determination of the absolute configuration at phosphorus of the diastereoisomers of adenosine 5′-(1-thiotriphosphate)

R. L. Jarvest and G. Lowe, J. Chem. Soc., Chem. Commun., 1979, 364
DOI: 10.1039/C39790000364

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