Issue 20, 1978

Preparative applications of metal vapours obtained by evaporation of metal powders from coated filaments: a new preparation of dibenzeneruthenium and observation of its limiting n.m.r. spectrum

Abstract

Ruthenium vapour, conveniently prepared by resistive heating of tungsten filaments coated with a mixture of ruthenium powder and epoxy resin, yields stable (Me2NPF2)5Ru and thermally unstable (C6H6)2Ru on condensation with Me2NPF2 and benzene respectively; the 1H n.m.r. spectrum of (C6H6)2Ru is consistent with a 1–4-η: 1–6-η formulation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 898-899

Preparative applications of metal vapours obtained by evaporation of metal powders from coated filaments: a new preparation of dibenzeneruthenium and observation of its limiting n.m.r. spectrum

P. L. Timms and R. B. King, J. Chem. Soc., Chem. Commun., 1978, 898 DOI: 10.1039/C39780000898

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