Issue 13, 1978
From the journal:

Journal of the Chemical Society, Chemical Communications

New mixed-metal clusters via metal hydride coupling. Synthesis and crystal structures of [(µ2-H)Os3W(CO)12(η5-C5H5)] and [(µ2-H)3Os3W(CO)11(η5-C5H5)]

Melvyn Rowen Churchill,   Frederick J. Hollander,   John R. Shapley  and  Daniel S. Foose  

Abstract

The reaction of [Os3(CO)10(NCMe)2] with the hydrido-complex [HW(CO)3(η5-C5H5)] under mild conditions yields the heteronuclear metal carbonyl hydride complexes [(µ2-H)Os3W(CO)12(η5-C5H5)](1) and [(µ2-H)3Os3W(CO)11(η5-C5H5)](2); the complexes have been characterized by X-ray diffraction studies and the locations of the bridging hydride ligands have been ascertained.

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Article information

DOI
https://doi.org/10.1039/C39780000534
Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 534-535

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New mixed-metal clusters via metal hydride coupling. Synthesis and crystal structures of [(µ2-H)Os3W(CO)12(η5-C5H5)] and [(µ2-H)3Os3W(CO)11(η5-C5H5)]

M. R. Churchill, F. J. Hollander, J. R. Shapley and D. S. Foose, J. Chem. Soc., Chem. Commun., 1978, 534 DOI: 10.1039/C39780000534

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