Issue 11, 1978

Selective synthesis of the nonachlorononaborate clusters B9Cl9 and B9Cl92–

Abstract

The redox relationship between dianionic and neutral boron clusters is demonstrated by the oxidation–chlorination of nonahydrononaborate (2–) with sulphuryl chloride to give the neutral nonachlorononaborate cluster, and its subsequent reduction back to the dianionic nonachlorononaborate(2–) species.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 462-463

Selective synthesis of the nonachlorononaborate clusters B9Cl9 and B9Cl92–

R. M. Kabbani and E. H. Wong, J. Chem. Soc., Chem. Commun., 1978, 462 DOI: 10.1039/C39780000462

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