SCHEDULED MAINTENANCE
Reduction of [Co(CO)4]– or [M(CO)3]4(M = Rh and Ir) with sodium in liquid ammonia, naphthalene–tetrahydrofuran, or hexamethylphosphoramide (only M = Rh and Ir) gives pyrophoric substances which provide the first main group 4 derivatives of [M(CO)3]3–(M = Co, Rh, and Ir) in 20–90% yields.
J. E. Ellis, P. T. Barger and M. L. Winzenburg, J. Chem. Soc., Chem. Commun., 1977, 686 DOI: 10.1039/C39770000686
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