SCHEDULED MAINTENANCE
Tryptamine and secologanin have been converted into akuammigine (7b), tetrahydroalstonine (7a), and ajmalicine (7c), in a highly regio- and stereo-selective sequence of reactions which duplicates the in vivo process; strictosidine (6a) is a precursor for 3α-alkaloids and vincoside (6b) for 3β.
R. T. Brown, J. Leonard and S. K. Sleigh, J. Chem. Soc., Chem. Commun., 1977, 636 DOI: 10.1039/C39770000636
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