The bridging acyl compounds [HOs3(COR)(CO)10](R = Ph, PhCH2, n-C5H11, n-C6H13, or Pri), derived from aldehydes, and the bridging enolato-compounds [HOs3(OCH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CR2)(CO)10](R = H, Me, or Ph), derived from ketens, give decarbonylated products at 150 °C, some by interconversion of these two forms.
K. A. Azam and A. J. Deeming, J. Chem. Soc., Chem. Commun., 1977, 472 DOI: 10.1039/C39770000472
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