Issue 15, 1976
From the journal:

Journal of the Chemical Society, Chemical Communications

Reaction of keten dithio-acetals with aziridine. Iodide ion-catalysed rearrangement of thio-aziridino-methylene compounds to novel Δ1-2-methylthio-3,3-disubstituted pyrrolines

Arvind Kumar,   Hiriyakkanavar Ila,   Hiriyakkanavar Junjappa  and  Sushila Mhatre  

Abstract

The keten dithioacetals (1) and (5) react readily with aziridine (2) to give the corresponding thioaziridinemethylene compounds (3) and (6) respectively, which on iodide ion-catalysed rearrangement, undergo ring expansion to give the pyrrolines (4) and (7) respectively.

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Article information

DOI
https://doi.org/10.1039/C39760000592
Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 592-593

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Reaction of keten dithio-acetals with aziridine. Iodide ion-catalysed rearrangement of thio-aziridino-methylene compounds to novel Δ1-2-methylthio-3,3-disubstituted pyrrolines

A. Kumar, H. Ila, H. Junjappa and S. Mhatre, J. Chem. Soc., Chem. Commun., 1976, 592 DOI: 10.1039/C39760000592

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