The first of three singlet electronic transitions associated with the double bond of a mono-olefin is assigned as the πx→ 3s Rydberg transition on the basis of far and vacuum u.v. absorption and c.d. measurements at ambient and low temperatures.
A. F. Drake, J. Chem. Soc., Chem. Commun., 1976, 515 DOI: 10.1039/C39760000515
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