Activation of a carbonyl group in cationic organometallic substrates such as the acylcyclopentadienylareneiron complexes(I), (V), and (VII) renders its electrochemical reduction easy and stereospecific, providing a route to the primary and secondary cationic alcohols (II) and (VI) or to the dinuclear dicationic pinacols (III).
E. Román, D. Astruc and A. Darchen, J. Chem. Soc., Chem. Commun., 1976, 512 DOI: 10.1039/C39760000512
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