Activation parameters for the solvolysis of t-butyl chloride in water–ethanol mixtures. Glycine as a transition state model

Abstract

Variations in ΔG^‡, ΔH^‡, and ΔS^‡ for the solvolysis of t-butyl chloride in water–ethanol mixtures are accounted for when glycine is used as a transition state model, provided that differences in molar volumes are taken into account.