The hydroxymethyl group of some carbohydrate molecules undergoes oxidative dimerisation with CrO3,2C5H5N, there being no evidence of an intermediate aldehyde having formed prior to the dimerisation.
M. B. Yunker and B. Fraser-Reid, J. Chem. Soc., Chem. Commun., 1975, 61 DOI: 10.1039/C39750000061
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